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Synthesis of mesostructured manganese phosphonate and its promising energy storage application

Journal Article


Abstract


  • Mesostructured manganese phosphonate (MnP) with a uniform nanorod morphology has been prepared through an easy surfactant-mediated procedure, in which cetyltrimethylammonium bromide acts as a structure-directing agent and 1-hydroxyethane 1,1-diphosphonic acid is used as the phosphonic bridging molecule. Suitable interaction between the micelles and precursors is proved to play an essential role in the formation of a mesophase. By optimizing the reaction conditions (e.g., Mn/P ratio, pH, and aging time), a mesostructure can be realized in manganese phosphonate. Furthermore, our MnP sample shows great potential as a high-performance pseudocapacitive material due to the abundant accessible active sites and rapid ion/electron transportation arising from the unique mesostructural architecture.

Authors


  •   Mei, Peng (external author)
  •   Pramanik, Malay (external author)
  •   Young, Christine (external author)
  •   Huang, Zhenguo (external author)
  •   Hossain, Md Shahriar
  •   Sugahara, Yoshiyuki (external author)
  •   Yamauchi, Yusuke (external author)

Publication Date


  • 2017

Citation


  • Mei, P., Pramanik, M., Young, C., Huang, Z., Hossain, M. A., Sugahara, Y. & Yamauchi, Y. (2017). Synthesis of mesostructured manganese phosphonate and its promising energy storage application. Journal of Materials Chemistry A, 5 (44), 23259-23266.

Scopus Eid


  • 2-s2.0-85034218763

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2831

Number Of Pages


  • 7

Start Page


  • 23259

End Page


  • 23266

Volume


  • 5

Issue


  • 44

Place Of Publication


  • United Kingdom

Abstract


  • Mesostructured manganese phosphonate (MnP) with a uniform nanorod morphology has been prepared through an easy surfactant-mediated procedure, in which cetyltrimethylammonium bromide acts as a structure-directing agent and 1-hydroxyethane 1,1-diphosphonic acid is used as the phosphonic bridging molecule. Suitable interaction between the micelles and precursors is proved to play an essential role in the formation of a mesophase. By optimizing the reaction conditions (e.g., Mn/P ratio, pH, and aging time), a mesostructure can be realized in manganese phosphonate. Furthermore, our MnP sample shows great potential as a high-performance pseudocapacitive material due to the abundant accessible active sites and rapid ion/electron transportation arising from the unique mesostructural architecture.

Authors


  •   Mei, Peng (external author)
  •   Pramanik, Malay (external author)
  •   Young, Christine (external author)
  •   Huang, Zhenguo (external author)
  •   Hossain, Md Shahriar
  •   Sugahara, Yoshiyuki (external author)
  •   Yamauchi, Yusuke (external author)

Publication Date


  • 2017

Citation


  • Mei, P., Pramanik, M., Young, C., Huang, Z., Hossain, M. A., Sugahara, Y. & Yamauchi, Y. (2017). Synthesis of mesostructured manganese phosphonate and its promising energy storage application. Journal of Materials Chemistry A, 5 (44), 23259-23266.

Scopus Eid


  • 2-s2.0-85034218763

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2831

Number Of Pages


  • 7

Start Page


  • 23259

End Page


  • 23266

Volume


  • 5

Issue


  • 44

Place Of Publication


  • United Kingdom