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Consecutive reduction, radical-cyclization, and oxidative-dehydrogenation reaction of ortho-substituted diboryl compounds

Journal Article


Abstract


  • An elegant synthetic route to a ladder-type di-borate compound 2a was reported based on the reduction, radical-cyclization, and oxidative-dehydrogenation reaction of 1. The existence of the biradical intermediate [1] 2- was supported by both EPR measurements and DFT calculations.

Authors


  •   Yu, Lirong (external author)
  •   Li, Yanglizhi (external author)
  •   Wang, Xi (external author)
  •   Wang, Xingyong
  •   Zhou, Panpan (external author)
  •   Jiang, Shangda (external author)
  •   Pan, Xiaobo (external author)

Publication Date


  • 2017

Citation


  • Yu, L., Li, Y., Wang, X., Wang, X., Zhou, P., Jiang, S. & Pan, X. (2017). Consecutive reduction, radical-cyclization, and oxidative-dehydrogenation reaction of ortho-substituted diboryl compounds. Chemical Communications, 53 (70), 9737-9740.

Scopus Eid


  • 2-s2.0-85028623161

Number Of Pages


  • 3

Start Page


  • 9737

End Page


  • 9740

Volume


  • 53

Issue


  • 70

Place Of Publication


  • United Kingdom

Abstract


  • An elegant synthetic route to a ladder-type di-borate compound 2a was reported based on the reduction, radical-cyclization, and oxidative-dehydrogenation reaction of 1. The existence of the biradical intermediate [1] 2- was supported by both EPR measurements and DFT calculations.

Authors


  •   Yu, Lirong (external author)
  •   Li, Yanglizhi (external author)
  •   Wang, Xi (external author)
  •   Wang, Xingyong
  •   Zhou, Panpan (external author)
  •   Jiang, Shangda (external author)
  •   Pan, Xiaobo (external author)

Publication Date


  • 2017

Citation


  • Yu, L., Li, Y., Wang, X., Wang, X., Zhou, P., Jiang, S. & Pan, X. (2017). Consecutive reduction, radical-cyclization, and oxidative-dehydrogenation reaction of ortho-substituted diboryl compounds. Chemical Communications, 53 (70), 9737-9740.

Scopus Eid


  • 2-s2.0-85028623161

Number Of Pages


  • 3

Start Page


  • 9737

End Page


  • 9740

Volume


  • 53

Issue


  • 70

Place Of Publication


  • United Kingdom