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Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage

Journal Article


Abstract


  • We present the synthesis and characterization of a unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12·χsolvent obtained via the supramolecular assembly between a non-centrosymmetric Dy(III) metalloligand and Cu(II) nitrate. Magnetic susceptibility measurements indicate that the complex behaves as a single-molecule magnet.

UOW Authors


  •   Li, Li (external author)
  •   Zhang, Yingjie (external author)
  •   Avdeev, Maxim (external author)
  •   Lindoy, Leonard F. (external author)
  •   Harman, David G. (external author)
  •   Zheng, Rongkun (external author)
  •   Cheng, Zhenxiang
  •   Aldrich-Wright, Janice R. (external author)
  •   Li, Kevin (external author)

Publication Date


  • 2016

Citation


  • Li, L., Zhang, Y., Avdeev, M., Lindoy, L. F., Harman, D. G., Zheng, R., Cheng, Z., Aldrich-Wright, J. R. & Li, F. (2016). Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage. Dalton Transactions: an international journal of inorganic chemistry, 45 9407-9411.

Scopus Eid


  • 2-s2.0-84973616635

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2524

Number Of Pages


  • 4

Start Page


  • 9407

End Page


  • 9411

Volume


  • 45

Abstract


  • We present the synthesis and characterization of a unique, slightly distorted square prismatic, box-like coordination cage of type [Cu6Dy8L8(MeOH)8(H2O)6](NO3)12·χsolvent obtained via the supramolecular assembly between a non-centrosymmetric Dy(III) metalloligand and Cu(II) nitrate. Magnetic susceptibility measurements indicate that the complex behaves as a single-molecule magnet.

UOW Authors


  •   Li, Li (external author)
  •   Zhang, Yingjie (external author)
  •   Avdeev, Maxim (external author)
  •   Lindoy, Leonard F. (external author)
  •   Harman, David G. (external author)
  •   Zheng, Rongkun (external author)
  •   Cheng, Zhenxiang
  •   Aldrich-Wright, Janice R. (external author)
  •   Li, Kevin (external author)

Publication Date


  • 2016

Citation


  • Li, L., Zhang, Y., Avdeev, M., Lindoy, L. F., Harman, D. G., Zheng, R., Cheng, Z., Aldrich-Wright, J. R. & Li, F. (2016). Self-assembly of a unique 3d/4f heterometallic square prismatic box-like coordination cage. Dalton Transactions: an international journal of inorganic chemistry, 45 9407-9411.

Scopus Eid


  • 2-s2.0-84973616635

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2524

Number Of Pages


  • 4

Start Page


  • 9407

End Page


  • 9411

Volume


  • 45