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Improved Reversibility of Fe3+/Fe4+ Redox Couple in Sodium Super Ion Conductor Type Na3Fe2(PO4)3 for Sodium-Ion Batteries

Journal Article


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Abstract


  • The methodology employed here utilizes the sodium super ion conductor type sodium iron phosphate wrapped with conducting carbon network to generate a stable Fe3+/Fe4+ redox   couple, thereby exhibiting higher operating voltage and energy density of sodium-ion batteries. This new class of sodium iron phosphate wrapped by carbon also displays a cycling stability with >96% capacity retention after 200 cycles.

Authors


  •   Rajagopalan, Ranjusha (external author)
  •   Chen, Bo (external author)
  •   Zhang, Zhicheng (external author)
  •   Wu, Xing Long. (external author)
  •   Du, Yonghua (external author)
  •   Huang, Ying (external author)
  •   Li, Bing (external author)
  •   Zong, Yun (external author)
  •   Wang, Jie (external author)
  •   Nam, Gwang-Hyeon (external author)
  •   Sindoro, Melinda (external author)
  •   Dou, Shi Xue
  •   Liu, Hua K.
  •   Zhang, Hua (external author)

Publication Date


  • 2017

Citation


  • Rajagopalan, R., Chen, B., Zhang, Z., Wu, X., Du, Y., Huang, Y., Li, B., Zong, Y., Wang, J., Nam, G., Sindoro, M., Dou, S. Xue., Liu, H. Kun. & Zhang, H. (2017). Improved Reversibility of Fe3+/Fe4+ Redox Couple in Sodium Super Ion Conductor Type Na3Fe2(PO4)3 for Sodium-Ion Batteries. Advanced Materials, 29 (12), 1605694-1.

Scopus Eid


  • 2-s2.0-85009977113

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=3448&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2425

Start Page


  • 1605694-1

Volume


  • 29

Issue


  • 12

Abstract


  • The methodology employed here utilizes the sodium super ion conductor type sodium iron phosphate wrapped with conducting carbon network to generate a stable Fe3+/Fe4+ redox   couple, thereby exhibiting higher operating voltage and energy density of sodium-ion batteries. This new class of sodium iron phosphate wrapped by carbon also displays a cycling stability with >96% capacity retention after 200 cycles.

Authors


  •   Rajagopalan, Ranjusha (external author)
  •   Chen, Bo (external author)
  •   Zhang, Zhicheng (external author)
  •   Wu, Xing Long. (external author)
  •   Du, Yonghua (external author)
  •   Huang, Ying (external author)
  •   Li, Bing (external author)
  •   Zong, Yun (external author)
  •   Wang, Jie (external author)
  •   Nam, Gwang-Hyeon (external author)
  •   Sindoro, Melinda (external author)
  •   Dou, Shi Xue
  •   Liu, Hua K.
  •   Zhang, Hua (external author)

Publication Date


  • 2017

Citation


  • Rajagopalan, R., Chen, B., Zhang, Z., Wu, X., Du, Y., Huang, Y., Li, B., Zong, Y., Wang, J., Nam, G., Sindoro, M., Dou, S. Xue., Liu, H. Kun. & Zhang, H. (2017). Improved Reversibility of Fe3+/Fe4+ Redox Couple in Sodium Super Ion Conductor Type Na3Fe2(PO4)3 for Sodium-Ion Batteries. Advanced Materials, 29 (12), 1605694-1.

Scopus Eid


  • 2-s2.0-85009977113

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=3448&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2425

Start Page


  • 1605694-1

Volume


  • 29

Issue


  • 12