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Effects of carbon content on the electrochemical performances of MoS2-C nanocomposites for Li-Ion batteries

Journal Article


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Abstract


  • Molybdenum disulfide is popular for rechargeable batteries, especially in Li-ion batteries, because of its layered structure and relatively high specific capacity. In this paper, we report MoS2-C nanocomposites that are synthesized by a hydrothermal process, and their use as anode material for Li-ion batteries. Ascorbic acid is used as the carbon source, and the carbon contents can be tuned from 2.5 wt % to 16.2 wt %. With increasing of carbon content, the morphology of MoS2-C nanocomposites changes from nanoflowers to nanospheres, and the particle size is decreased from 200 to 60 nm. This change is caused by the chemical complex interaction of ascorbic acid. The MoS2-C nanocomposite with 8.4 wt % C features a high capacity of 970 mAh g-1 and sustains a capacity retention ratio of nearly 100% after 100 cycles. When the current increases to 1000 mA g-1, the capacity still reaches 730 mAh g-1. The above manifests that the carbon coating layer does not only accelerate the charge transfer kinetics to supply quick discharging and charging, but also hold the integrity of the electrode materials as evidenced by the long cycling stability. Therefore, MoS2-based nanocomposites could be used as commercial anode materials in Li-ion batteries.

UOW Authors


  •   Sun, Weiyi (external author)
  •   Hu, Zhe (external author)
  •   Wang, Caiyun
  •   Tao, Zhanliang (external author)
  •   Chou, Shulei
  •   Kang, Yong-Mook (external author)
  •   Liu, Hua

Publication Date


  • 2016

Citation


  • Sun, W., Hu, Z., Wang, C., Tao, Z., Chou, S., Kang, Y. & Liu, H. (2016). Effects of carbon content on the electrochemical performances of MoS2-C nanocomposites for Li-Ion batteries. ACS Applied Materials and Interfaces, 8 (34), 22168-22174.

Scopus Eid


  • 2-s2.0-84984985907

Ro Full-text Url


  • https://ro.uow.edu.au/cgi/viewcontent.cgi?article=3236&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2215

Has Global Citation Frequency


Number Of Pages


  • 6

Start Page


  • 22168

End Page


  • 22174

Volume


  • 8

Issue


  • 34

Place Of Publication


  • United States

Abstract


  • Molybdenum disulfide is popular for rechargeable batteries, especially in Li-ion batteries, because of its layered structure and relatively high specific capacity. In this paper, we report MoS2-C nanocomposites that are synthesized by a hydrothermal process, and their use as anode material for Li-ion batteries. Ascorbic acid is used as the carbon source, and the carbon contents can be tuned from 2.5 wt % to 16.2 wt %. With increasing of carbon content, the morphology of MoS2-C nanocomposites changes from nanoflowers to nanospheres, and the particle size is decreased from 200 to 60 nm. This change is caused by the chemical complex interaction of ascorbic acid. The MoS2-C nanocomposite with 8.4 wt % C features a high capacity of 970 mAh g-1 and sustains a capacity retention ratio of nearly 100% after 100 cycles. When the current increases to 1000 mA g-1, the capacity still reaches 730 mAh g-1. The above manifests that the carbon coating layer does not only accelerate the charge transfer kinetics to supply quick discharging and charging, but also hold the integrity of the electrode materials as evidenced by the long cycling stability. Therefore, MoS2-based nanocomposites could be used as commercial anode materials in Li-ion batteries.

UOW Authors


  •   Sun, Weiyi (external author)
  •   Hu, Zhe (external author)
  •   Wang, Caiyun
  •   Tao, Zhanliang (external author)
  •   Chou, Shulei
  •   Kang, Yong-Mook (external author)
  •   Liu, Hua

Publication Date


  • 2016

Citation


  • Sun, W., Hu, Z., Wang, C., Tao, Z., Chou, S., Kang, Y. & Liu, H. (2016). Effects of carbon content on the electrochemical performances of MoS2-C nanocomposites for Li-Ion batteries. ACS Applied Materials and Interfaces, 8 (34), 22168-22174.

Scopus Eid


  • 2-s2.0-84984985907

Ro Full-text Url


  • https://ro.uow.edu.au/cgi/viewcontent.cgi?article=3236&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2215

Has Global Citation Frequency


Number Of Pages


  • 6

Start Page


  • 22168

End Page


  • 22174

Volume


  • 8

Issue


  • 34

Place Of Publication


  • United States