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Synthesis, characterization, and structures of a persistent aniline radical cation

Journal Article


Abstract


  • Feeling the heat: The aniline radical cation TBA.+ (TBA=2,4,6-tBu3C6H2NH2) has been successfully stabilized both in solution and in the solid state. It exists as two isomers in the crystal lattice that interchange with temperature, and features an exceptionally long C-N bond beyond theoretical prediction.

Authors


  •   Chen, Xiaoyu (external author)
  •   Wang, Xingyong
  •   Sui, Yunxia (external author)
  •   Li, Yizhi (external author)
  •   Ma, Jing (external author)
  •   Zuo, Jing-Lin (external author)
  •   Wang, Xinping (external author)

Publication Date


  • 2012

Citation


  • Chen, X., Wang, X., Sui, Y., Li, Y., Ma, J., Zuo, J. & Wang, X. (2012). Synthesis, characterization, and structures of a persistent aniline radical cation. Angewandte Chemie International Edition, 51 (47), 11878-11881.

Scopus Eid


  • 2-s2.0-84869459730

Ro Metadata Url


  • http://ro.uow.edu.au/smhpapers/3925

Number Of Pages


  • 3

Start Page


  • 11878

End Page


  • 11881

Volume


  • 51

Issue


  • 47

Abstract


  • Feeling the heat: The aniline radical cation TBA.+ (TBA=2,4,6-tBu3C6H2NH2) has been successfully stabilized both in solution and in the solid state. It exists as two isomers in the crystal lattice that interchange with temperature, and features an exceptionally long C-N bond beyond theoretical prediction.

Authors


  •   Chen, Xiaoyu (external author)
  •   Wang, Xingyong
  •   Sui, Yunxia (external author)
  •   Li, Yizhi (external author)
  •   Ma, Jing (external author)
  •   Zuo, Jing-Lin (external author)
  •   Wang, Xinping (external author)

Publication Date


  • 2012

Citation


  • Chen, X., Wang, X., Sui, Y., Li, Y., Ma, J., Zuo, J. & Wang, X. (2012). Synthesis, characterization, and structures of a persistent aniline radical cation. Angewandte Chemie International Edition, 51 (47), 11878-11881.

Scopus Eid


  • 2-s2.0-84869459730

Ro Metadata Url


  • http://ro.uow.edu.au/smhpapers/3925

Number Of Pages


  • 3

Start Page


  • 11878

End Page


  • 11881

Volume


  • 51

Issue


  • 47