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Two phosphaalkene radical cations with inverse spin density distributions

Journal Article


Abstract


  • Two phosphaalkene radical cations 1•+ and 2•+ have been reported. 1•+ is stable in the solid state and has been structurally characterized. 2•+ only remains persistent in solution. 1•+ is described as a phosphorus-centered radical, while 2•+ as a delocalized radical with little contribution from phosphorus.

Authors


  •   Pan, Xiaobo (external author)
  •   Wang, Xingyong
  •   Zhang, Zaichao (external author)
  •   Wang, Xinping (external author)

Publication Date


  • 2015

Geographic Focus


Citation


  • Pan, X., Wang, X., Zhang, Z. & Wang, X. (2015). Two phosphaalkene radical cations with inverse spin density distributions. Dalton Transactions: an international journal of inorganic chemistry, 44 (34), 15099-15102.

Scopus Eid


  • 2-s2.0-84939615562

Ro Metadata Url


  • http://ro.uow.edu.au/smhpapers/3906

Has Global Citation Frequency


Number Of Pages


  • 3

Start Page


  • 15099

End Page


  • 15102

Volume


  • 44

Issue


  • 34

Place Of Publication


  • United Kingdom

Abstract


  • Two phosphaalkene radical cations 1•+ and 2•+ have been reported. 1•+ is stable in the solid state and has been structurally characterized. 2•+ only remains persistent in solution. 1•+ is described as a phosphorus-centered radical, while 2•+ as a delocalized radical with little contribution from phosphorus.

Authors


  •   Pan, Xiaobo (external author)
  •   Wang, Xingyong
  •   Zhang, Zaichao (external author)
  •   Wang, Xinping (external author)

Publication Date


  • 2015

Geographic Focus


Citation


  • Pan, X., Wang, X., Zhang, Z. & Wang, X. (2015). Two phosphaalkene radical cations with inverse spin density distributions. Dalton Transactions: an international journal of inorganic chemistry, 44 (34), 15099-15102.

Scopus Eid


  • 2-s2.0-84939615562

Ro Metadata Url


  • http://ro.uow.edu.au/smhpapers/3906

Has Global Citation Frequency


Number Of Pages


  • 3

Start Page


  • 15099

End Page


  • 15102

Volume


  • 44

Issue


  • 34

Place Of Publication


  • United Kingdom