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Effect of π-conjugation on electrochemical properties of poly(terthiophene)s 3′-substituted with fullerene C60

Journal Article


Abstract


  • The series of copolymers based on terthiophene 3′-substituted with C60-pyrrolidine or styryl group, were electrochemically synthesized and characterized. The dense distribution of C60 side group caused the steric effects between them and the perturbation in the extent of π-electron delocalization of the poly(terthiophene) backbone. The ESR spectroscopy showed the presence of close-packed clusters especially in homopolymer: poly(terthiophene-C60). The oxidative electrochemical copolymerization of terthiophene units was performed to avoid this steric interactions and in results to extend the effective π-conjugation length in the polymer. The use of different ratio of the co-monomers contributed to the variable distribution of C60 unit and different effective π-conjugation of the resulting polymers. Those changes affected electrochemical and photocurrent-generating properties of these materials.

Publication Date


  • 2016

Citation


  • Czichy, M., Wagner, P., Lapkowski, M. & Officer, D. L. (2016). Effect of π-conjugation on electrochemical properties of poly(terthiophene)s 3′-substituted with fullerene C60. Journal of Electroanalytical Chemistry, 772 103-109.

Scopus Eid


  • 2-s2.0-84965097011

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2073

Number Of Pages


  • 6

Start Page


  • 103

End Page


  • 109

Volume


  • 772

Abstract


  • The series of copolymers based on terthiophene 3′-substituted with C60-pyrrolidine or styryl group, were electrochemically synthesized and characterized. The dense distribution of C60 side group caused the steric effects between them and the perturbation in the extent of π-electron delocalization of the poly(terthiophene) backbone. The ESR spectroscopy showed the presence of close-packed clusters especially in homopolymer: poly(terthiophene-C60). The oxidative electrochemical copolymerization of terthiophene units was performed to avoid this steric interactions and in results to extend the effective π-conjugation length in the polymer. The use of different ratio of the co-monomers contributed to the variable distribution of C60 unit and different effective π-conjugation of the resulting polymers. Those changes affected electrochemical and photocurrent-generating properties of these materials.

Publication Date


  • 2016

Citation


  • Czichy, M., Wagner, P., Lapkowski, M. & Officer, D. L. (2016). Effect of π-conjugation on electrochemical properties of poly(terthiophene)s 3′-substituted with fullerene C60. Journal of Electroanalytical Chemistry, 772 103-109.

Scopus Eid


  • 2-s2.0-84965097011

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2073

Number Of Pages


  • 6

Start Page


  • 103

End Page


  • 109

Volume


  • 772