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Effect of grain size on the energy storage properties of (Ba0.4Sr0.6)TiO3 paraelectric ceramics

Journal Article


Abstract


  • (Ba0.4Sr0.6)TiO3 (BST) ceramics with various grain sizes (0.5-5.6μm) were prepared by conventional solid state reaction methods. The effect of grain size on the energy storage properties of BST ceramics (Tc≈-65°C) was investigated. With decreasing grain sizes, a clear tendency toward the diffuse phase transition was observed and the dielectric nonlinearity was reduced gradually, which can be explained by the Devonshire's phenomenological theory (from the viewpoint of intrinsic polarization). Based on the multi-polarization mechanism model, the relationship between the polarization behavior of polar nano-regions (the extrinsic nonlinear polarization mechanisms) and grain size was studied. The variation of the grain boundary density was thought to play an important role on the improvement of dielectric breakdown strength, account for the enhanced energy density, which was confirmed by the complex impedance spectroscopy analysis based on a double-layered dielectric model. © 2013 Elsevier Ltd.

UOW Authors


  •   Song, Zhe (external author)
  •   Liu, Hanxing (external author)
  •   Zhang, Shujun
  •   Wang, Zhijian (external author)
  •   Shi, Yatong (external author)
  •   Hao, Hua (external author)
  •   Cao, Minghe (external author)
  •   Yao, Zhonghua (external author)
  •   Yu, Zhiyong (external author)

Publication Date


  • 2014

Citation


  • Song, Z., Liu, H., Zhang, S., Wang, Z., Shi, Y., Hao, H., Cao, M., Yao, Z. & Yu, Z. (2014). Effect of grain size on the energy storage properties of (Ba0.4Sr0.6)TiO3 paraelectric ceramics. Journal of the European Ceramic Society, 34 (5), 1209-1217.

Scopus Eid


  • 2-s2.0-84892482639

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1878

Has Global Citation Frequency


Number Of Pages


  • 8

Start Page


  • 1209

End Page


  • 1217

Volume


  • 34

Issue


  • 5

Place Of Publication


  • United Kingdom

Abstract


  • (Ba0.4Sr0.6)TiO3 (BST) ceramics with various grain sizes (0.5-5.6μm) were prepared by conventional solid state reaction methods. The effect of grain size on the energy storage properties of BST ceramics (Tc≈-65°C) was investigated. With decreasing grain sizes, a clear tendency toward the diffuse phase transition was observed and the dielectric nonlinearity was reduced gradually, which can be explained by the Devonshire's phenomenological theory (from the viewpoint of intrinsic polarization). Based on the multi-polarization mechanism model, the relationship between the polarization behavior of polar nano-regions (the extrinsic nonlinear polarization mechanisms) and grain size was studied. The variation of the grain boundary density was thought to play an important role on the improvement of dielectric breakdown strength, account for the enhanced energy density, which was confirmed by the complex impedance spectroscopy analysis based on a double-layered dielectric model. © 2013 Elsevier Ltd.

UOW Authors


  •   Song, Zhe (external author)
  •   Liu, Hanxing (external author)
  •   Zhang, Shujun
  •   Wang, Zhijian (external author)
  •   Shi, Yatong (external author)
  •   Hao, Hua (external author)
  •   Cao, Minghe (external author)
  •   Yao, Zhonghua (external author)
  •   Yu, Zhiyong (external author)

Publication Date


  • 2014

Citation


  • Song, Z., Liu, H., Zhang, S., Wang, Z., Shi, Y., Hao, H., Cao, M., Yao, Z. & Yu, Z. (2014). Effect of grain size on the energy storage properties of (Ba0.4Sr0.6)TiO3 paraelectric ceramics. Journal of the European Ceramic Society, 34 (5), 1209-1217.

Scopus Eid


  • 2-s2.0-84892482639

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1878

Has Global Citation Frequency


Number Of Pages


  • 8

Start Page


  • 1209

End Page


  • 1217

Volume


  • 34

Issue


  • 5

Place Of Publication


  • United Kingdom