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Polarization alignment, phase transition, and piezoelectricity development in polycrystalline 0.5Ba(Zr0.2 Ti0.8)O3-0.5(Ba0.7 Ca0.3)TiO3

Journal Article


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Abstract


  • The microstructural origin of the exceptionally high piezoelectric response of polycrystalline 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 is investigated using in situ transmission electron microscopy, in addition to a wide variety of bulk measurements and first-principles calculations. A direct correlation is established relating a domain wall-free state to the ultrahigh piezoelectric d33 coefficient in this BaTiO3-based composition. The results suggest that the unique single-domain state formed during electrical poling is a result of a structural transition from coexistent rhombohedral and tetragonal phases to an orthorhombic phase that has an anomalously low elastic modulus. First-principles calculations indicate that incorporating Ca2+ and Zr4+ into BaTiO3 reduces the differences in structure and energy of the variant perovskite phases, and 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 is identified as unique because the variant phases become almost indistinguishable. The structural instability and elastic softening observed here are responsible for the excellent piezoelectric properties of this lead-free ceramic. © 2014 American Physical Society.

UOW Authors


  •   Guo, Hanzheng (external author)
  •   Voas, Brian K. (external author)
  •   Zhang, Shujun
  •   Zhou, Chao (external author)
  •   Ren, Xiaobing (external author)
  •   Beckman, Scott P. (external author)
  •   Tan, Xiaoli (external author)

Publication Date


  • 2014

Citation


  • Guo, H., Voas, B. K., Zhang, S., Zhou, C., Ren, X., Beckman, S. P. & Tan, X. (2014). Polarization alignment, phase transition, and piezoelectricity development in polycrystalline 0.5Ba(Zr0.2 Ti0.8)O3-0.5(Ba0.7 Ca0.3)TiO3. Physical Review B: Condensed Matter and Materials Physics, 90 (1), 014103-1-014103-10.

Scopus Eid


  • 2-s2.0-84904693328

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=2877&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1875

Has Global Citation Frequency


Start Page


  • 014103-1

End Page


  • 014103-10

Volume


  • 90

Issue


  • 1

Place Of Publication


  • United States

Abstract


  • The microstructural origin of the exceptionally high piezoelectric response of polycrystalline 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 is investigated using in situ transmission electron microscopy, in addition to a wide variety of bulk measurements and first-principles calculations. A direct correlation is established relating a domain wall-free state to the ultrahigh piezoelectric d33 coefficient in this BaTiO3-based composition. The results suggest that the unique single-domain state formed during electrical poling is a result of a structural transition from coexistent rhombohedral and tetragonal phases to an orthorhombic phase that has an anomalously low elastic modulus. First-principles calculations indicate that incorporating Ca2+ and Zr4+ into BaTiO3 reduces the differences in structure and energy of the variant perovskite phases, and 0.5Ba(Zr0.2Ti0.8)O3-0.5(Ba0.7Ca0.3)TiO3 is identified as unique because the variant phases become almost indistinguishable. The structural instability and elastic softening observed here are responsible for the excellent piezoelectric properties of this lead-free ceramic. © 2014 American Physical Society.

UOW Authors


  •   Guo, Hanzheng (external author)
  •   Voas, Brian K. (external author)
  •   Zhang, Shujun
  •   Zhou, Chao (external author)
  •   Ren, Xiaobing (external author)
  •   Beckman, Scott P. (external author)
  •   Tan, Xiaoli (external author)

Publication Date


  • 2014

Citation


  • Guo, H., Voas, B. K., Zhang, S., Zhou, C., Ren, X., Beckman, S. P. & Tan, X. (2014). Polarization alignment, phase transition, and piezoelectricity development in polycrystalline 0.5Ba(Zr0.2 Ti0.8)O3-0.5(Ba0.7 Ca0.3)TiO3. Physical Review B: Condensed Matter and Materials Physics, 90 (1), 014103-1-014103-10.

Scopus Eid


  • 2-s2.0-84904693328

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=2877&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1875

Has Global Citation Frequency


Start Page


  • 014103-1

End Page


  • 014103-10

Volume


  • 90

Issue


  • 1

Place Of Publication


  • United States