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Synthesis and electrochemical performances of MnxCoyNizCO3 as novel anode material

Journal Article


Abstract


  • Hydrothermal method was used to synthesize Mn x Co y Ni z CO3 with morphology of microspheres. When the reactants MnSO4·H2O, CoSO4·7H2O and NiSO4·6H2O were in the molar ratio of 0.54:0.13:0.26, the product was Mn0.756Co0.133Ni0.111CO3, demonstrating the best electrochemical performances among all the prepared samples. The reversible discharge capacity of Mn0.756Co0.133Ni0.111CO3 maintained at 754mAhg-1 after 200 cycles at the current density of 100mAg-1 in the voltage range of 0.01-3V. The ternary manganese-nickel-cobalt carbonates with suitable composition could be used as novel anode material for lithium-ion battery application.

Authors


  •   Li, Qing (external author)
  •   Feng, Chuanqi (external author)
  •   Guo, Zaiping

Publication Date


  • 2016

Citation


  • Li, Q., Feng, C. & Guo, Z. (2016). Synthesis and electrochemical performances of MnxCoyNizCO3 as novel anode material. Ceramics International, 42 (6), 7888-7894.

Scopus Eid


  • 2-s2.0-84960121102

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2056

Has Global Citation Frequency


Number Of Pages


  • 6

Start Page


  • 7888

End Page


  • 7894

Volume


  • 42

Issue


  • 6

Place Of Publication


  • United Kingdom

Abstract


  • Hydrothermal method was used to synthesize Mn x Co y Ni z CO3 with morphology of microspheres. When the reactants MnSO4·H2O, CoSO4·7H2O and NiSO4·6H2O were in the molar ratio of 0.54:0.13:0.26, the product was Mn0.756Co0.133Ni0.111CO3, demonstrating the best electrochemical performances among all the prepared samples. The reversible discharge capacity of Mn0.756Co0.133Ni0.111CO3 maintained at 754mAhg-1 after 200 cycles at the current density of 100mAg-1 in the voltage range of 0.01-3V. The ternary manganese-nickel-cobalt carbonates with suitable composition could be used as novel anode material for lithium-ion battery application.

Authors


  •   Li, Qing (external author)
  •   Feng, Chuanqi (external author)
  •   Guo, Zaiping

Publication Date


  • 2016

Citation


  • Li, Q., Feng, C. & Guo, Z. (2016). Synthesis and electrochemical performances of MnxCoyNizCO3 as novel anode material. Ceramics International, 42 (6), 7888-7894.

Scopus Eid


  • 2-s2.0-84960121102

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2056

Has Global Citation Frequency


Number Of Pages


  • 6

Start Page


  • 7888

End Page


  • 7894

Volume


  • 42

Issue


  • 6

Place Of Publication


  • United Kingdom