Skip to main content
placeholder image

Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids

Journal Article


Download full-text (Open Access)

Abstract


  • © 2016 The Royal Society of Chemistry. Combining ferrocene and iodine results in enhanced thermoelectrochemical (or thermogalvanic) waste heat harvesting abilities, for both the Seebeck coefficient and the overall power output. All systems displayed a mixture of ferrocene, ferrocenium, iodine and triiodide. The observed enhancement correlates with lower electron-density on the ferrocene; the synergistic improvement observed for mixtures of substituted ferrocenes and iodine is attributed to the formation of charge-transfer complexes. Combining dibutanoylferrocene and iodine resulted in the highest Seebeck coefficient of 1.67 mV K-1.

Authors


  •   Anari, E H.B. (external author)
  •   Romano, Mark S. (external author)
  •   Teh, W X. (external author)
  •   Black, J J. (external author)
  •   Jiang, E (external author)
  •   Chen, Jun
  •   To, T Q. (external author)
  •   Panchompoo, J (external author)
  •   Aldous, Leigh (external author)

Publication Date


  • 2016

Citation


  • Anari, E. H.B., Romano, M., Teh, W. X., Black, J. J., Jiang, E., Chen, J., To, T. Q., Panchompoo, J. & Aldous, L. (2016). Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids. Chemical Communications, 52 (4), 745-748.

Scopus Eid


  • 2-s2.0-84953291224

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=2908&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1906

Has Global Citation Frequency


Number Of Pages


  • 3

Start Page


  • 745

End Page


  • 748

Volume


  • 52

Issue


  • 4

Place Of Publication


  • United Kingdom

Abstract


  • © 2016 The Royal Society of Chemistry. Combining ferrocene and iodine results in enhanced thermoelectrochemical (or thermogalvanic) waste heat harvesting abilities, for both the Seebeck coefficient and the overall power output. All systems displayed a mixture of ferrocene, ferrocenium, iodine and triiodide. The observed enhancement correlates with lower electron-density on the ferrocene; the synergistic improvement observed for mixtures of substituted ferrocenes and iodine is attributed to the formation of charge-transfer complexes. Combining dibutanoylferrocene and iodine resulted in the highest Seebeck coefficient of 1.67 mV K-1.

Authors


  •   Anari, E H.B. (external author)
  •   Romano, Mark S. (external author)
  •   Teh, W X. (external author)
  •   Black, J J. (external author)
  •   Jiang, E (external author)
  •   Chen, Jun
  •   To, T Q. (external author)
  •   Panchompoo, J (external author)
  •   Aldous, Leigh (external author)

Publication Date


  • 2016

Citation


  • Anari, E. H.B., Romano, M., Teh, W. X., Black, J. J., Jiang, E., Chen, J., To, T. Q., Panchompoo, J. & Aldous, L. (2016). Substituted ferrocenes and iodine as synergistic thermoelectrochemical heat harvesting redox couples in ionic liquids. Chemical Communications, 52 (4), 745-748.

Scopus Eid


  • 2-s2.0-84953291224

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=2908&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1906

Has Global Citation Frequency


Number Of Pages


  • 3

Start Page


  • 745

End Page


  • 748

Volume


  • 52

Issue


  • 4

Place Of Publication


  • United Kingdom