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Graphite-nanoplate-coated Bi2S3 composite with high-volume energy density and excellent cycle life for room-temperature sodium-sulfide batteries

Journal Article


Abstract


  • Graphite-nanoplate-coated Bi2S3 composite (Bi2S3@C) has been prepared by a simple, scalable, and energy-efficient precipitation method combined with ball milling. The Bi2S3@C composite was used as the cathode material for sodium–sulfide batteries. It delivered an initial capacity of 550 mAh g−1 and high stable specific energy in the range of 275–300 Wh kg−1 at 0.1 C, with an enhanced capacity retention of 69 % over 100 cycles. The unique structure demonstrates superior cycling stability, with a capacity drop of 0.3 % per cycle over 100 cycles, compared with that of bare Bi2S3. The sodium storage mechanism of Bi2S3 was investigated based on ex situ X-ray diffraction and scanning transmission electron microscopy.

Publication Date


  • 2016

Citation


  • Li, W., Han, C., Chou, S., Wang, J., Li, Z., Kang, Y., Liu, H. & Dou, S. (2016). Graphite-nanoplate-coated Bi2S3 composite with high-volume energy density and excellent cycle life for room-temperature sodium-sulfide batteries. Chemistry : a European journal, 22 (2), 590-597.

Scopus Eid


  • 2-s2.0-84952758947

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2111

Number Of Pages


  • 7

Start Page


  • 590

End Page


  • 597

Volume


  • 22

Issue


  • 2

Abstract


  • Graphite-nanoplate-coated Bi2S3 composite (Bi2S3@C) has been prepared by a simple, scalable, and energy-efficient precipitation method combined with ball milling. The Bi2S3@C composite was used as the cathode material for sodium–sulfide batteries. It delivered an initial capacity of 550 mAh g−1 and high stable specific energy in the range of 275–300 Wh kg−1 at 0.1 C, with an enhanced capacity retention of 69 % over 100 cycles. The unique structure demonstrates superior cycling stability, with a capacity drop of 0.3 % per cycle over 100 cycles, compared with that of bare Bi2S3. The sodium storage mechanism of Bi2S3 was investigated based on ex situ X-ray diffraction and scanning transmission electron microscopy.

Publication Date


  • 2016

Citation


  • Li, W., Han, C., Chou, S., Wang, J., Li, Z., Kang, Y., Liu, H. & Dou, S. (2016). Graphite-nanoplate-coated Bi2S3 composite with high-volume energy density and excellent cycle life for room-temperature sodium-sulfide batteries. Chemistry : a European journal, 22 (2), 590-597.

Scopus Eid


  • 2-s2.0-84952758947

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/2111

Number Of Pages


  • 7

Start Page


  • 590

End Page


  • 597

Volume


  • 22

Issue


  • 2