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The spontaneous formation of single-molecule junctions via terminal alkynes

Journal Article


Abstract


  • Herein, we report the spontaneous formation of single-molecule junctions via terminal alkyne contact groups. Self-assembled monolayers that form spontaneously from diluted solutions of 1, 4-diethynylbenzene (DEB) were used to build single-molecule contacts and assessed using the scanning tunneling microscopy-break junction technique (STM-BJ). The STM-BJ technique in both its dynamic and static approaches was used to characterize the lifetime (stability) and the conductivity of a single-DEB wire. It is demonstrated that single-molecule junctions form spontaneously with terminal alkynes and require no electrochemical control or chemical deprotonation. The alkyne anchoring group was compared against typical contact groups exploited in single-molecule studies, i.e. amine (benzenediamine) and thiol (benzendithiol) contact groups. The alkyne contact showed a conductance magnitude comparable to that observed with amine and thiol groups. The lifetime of the junctions formed from alkynes were only slightly less than that of thiols and greater than that observed for amines. These findings are important as (a) they extend the repertoire of chemical contacts used in single-molecule measurements to 1-alkynes, which are synthetically accessible and stable and (b) alkynes have a remarkable affinity toward silicon surfaces, hence opening the door for the study of single-molecule transport on a semiconducting electronic platform.

Authors


  •   Pla-Vilanova, Pepita (external author)
  •   Aragones, Albert C. (external author)
  •   Ciampi, Simone (external author)
  •   Sanz, Fausto (external author)
  •   Darwish, Nadim A. (external author)
  •   Diez-Perez, Ismael (external author)

Publication Date


  • 2015

Citation


  • Pla-Vilanova, P., Aragones, A. C., Ciampi, S., Sanz, F., Darwish, N. & Diez-Perez, I. (2015). The spontaneous formation of single-molecule junctions via terminal alkynes. Nanotechnology, 26 (38), 381001-1-381001-7.

Scopus Eid


  • 2-s2.0-84940850948

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1604

Has Global Citation Frequency


Start Page


  • 381001-1

End Page


  • 381001-7

Volume


  • 26

Issue


  • 38

Place Of Publication


  • United Kingdom

Abstract


  • Herein, we report the spontaneous formation of single-molecule junctions via terminal alkyne contact groups. Self-assembled monolayers that form spontaneously from diluted solutions of 1, 4-diethynylbenzene (DEB) were used to build single-molecule contacts and assessed using the scanning tunneling microscopy-break junction technique (STM-BJ). The STM-BJ technique in both its dynamic and static approaches was used to characterize the lifetime (stability) and the conductivity of a single-DEB wire. It is demonstrated that single-molecule junctions form spontaneously with terminal alkynes and require no electrochemical control or chemical deprotonation. The alkyne anchoring group was compared against typical contact groups exploited in single-molecule studies, i.e. amine (benzenediamine) and thiol (benzendithiol) contact groups. The alkyne contact showed a conductance magnitude comparable to that observed with amine and thiol groups. The lifetime of the junctions formed from alkynes were only slightly less than that of thiols and greater than that observed for amines. These findings are important as (a) they extend the repertoire of chemical contacts used in single-molecule measurements to 1-alkynes, which are synthetically accessible and stable and (b) alkynes have a remarkable affinity toward silicon surfaces, hence opening the door for the study of single-molecule transport on a semiconducting electronic platform.

Authors


  •   Pla-Vilanova, Pepita (external author)
  •   Aragones, Albert C. (external author)
  •   Ciampi, Simone (external author)
  •   Sanz, Fausto (external author)
  •   Darwish, Nadim A. (external author)
  •   Diez-Perez, Ismael (external author)

Publication Date


  • 2015

Citation


  • Pla-Vilanova, P., Aragones, A. C., Ciampi, S., Sanz, F., Darwish, N. & Diez-Perez, I. (2015). The spontaneous formation of single-molecule junctions via terminal alkynes. Nanotechnology, 26 (38), 381001-1-381001-7.

Scopus Eid


  • 2-s2.0-84940850948

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1604

Has Global Citation Frequency


Start Page


  • 381001-1

End Page


  • 381001-7

Volume


  • 26

Issue


  • 38

Place Of Publication


  • United Kingdom