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2-(10′,10′-Dimethyl-3′-sulfanylidene-4′- azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4- azatricyclo[5.2.1.01,5]decane-3-thione

Journal Article


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Abstract


  • The title compound, C28H40N2O2S2, was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionylthiolactam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conformation along the central C-C bond with a C-C-C-C- torsion angle of 20.4 (3)°.

UOW Authors


  •   Walker, Ashley (external author)
  •   Forsyth, Craig M. (external author)
  •   Perlmutter, Patrick (external author)

Publication Date


  • 2013

Citation


  • Walker, A., Forsyth, C. M. & Perlmutter, P. (2013). 2-(10′,10′-Dimethyl-3′-sulfanylidene-4′- azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4- azatricyclo[5.2.1.01,5]decane-3-thione. Acta Crystallographica Section E: Structure Reports Online, E69 (8), o1282-1-o1282-7.

Scopus Eid


  • 2-s2.0-84881469638

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=2521&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1519

Start Page


  • o1282-1

End Page


  • o1282-7

Volume


  • E69

Issue


  • 8

Abstract


  • The title compound, C28H40N2O2S2, was obtained as a minor product from an anti-aldol reaction between the corresponding N-propionylthiolactam and benzaldehyde. The asymmetric unit contains one half-molecule, which is completed by inversion symmetry. The molecule displays a nearly eclipsed conformation along the central C-C bond with a C-C-C-C- torsion angle of 20.4 (3)°.

UOW Authors


  •   Walker, Ashley (external author)
  •   Forsyth, Craig M. (external author)
  •   Perlmutter, Patrick (external author)

Publication Date


  • 2013

Citation


  • Walker, A., Forsyth, C. M. & Perlmutter, P. (2013). 2-(10′,10′-Dimethyl-3′-sulfanylidene-4′- azatricyclo[5.2.1.01,5]decan-2′-yl)-10,10-dimethyl-4- azatricyclo[5.2.1.01,5]decane-3-thione. Acta Crystallographica Section E: Structure Reports Online, E69 (8), o1282-1-o1282-7.

Scopus Eid


  • 2-s2.0-84881469638

Ro Full-text Url


  • http://ro.uow.edu.au/cgi/viewcontent.cgi?article=2521&context=aiimpapers

Ro Metadata Url


  • http://ro.uow.edu.au/aiimpapers/1519

Start Page


  • o1282-1

End Page


  • o1282-7

Volume


  • E69

Issue


  • 8